Leonard Kollender Nash, American chemistry professor. Numerous problems appear throughout the text, in addition to 30 fully worked illustrative examples.
#Elements of statistical thermodynamics nash free
The consequences of thermodynamic principles are examined in chapters on the free energies, the Clapeyron equation, ideal solutions and colligative properties, and the equilibrium state and equilibrium constant. Considerations of the second principle of thermodynamics encompass the Carnot cycle, the concept of entropy, and evaluation of entropy changes. The first principle of thermodynamics is explored in terms of energy, enthalpy, thermochemistry and Hess's Law, heat capacity, Kirchhoff's equations, and adiabatic processes. Readers need no more than a sound background in high school mathematics and physics, as well as some familiarity with the leading quantitative concepts of an introductory college chemistry course.Īn introduction establishes the fundamentals of temperature, heat and work, reversibility, and pressure-volume work. Methods are limited to a very few of the most elementary operations of the calculus, all of which are explained in an appendix. Its argument highlights the physical content of thermodynamics, as distinct from purely mathematical aspects. This text addresses the use of purely thermal data in calculating the position of equilibrium in a chemical reaction. This text addresses the use of purely thermal data in c.) Appropriate for introductory college chemistry courses, it further lends itself to use as a supplementary text for independent study by more advanced students.Įlements of Chemical Thermodynamics: Second Edition (Dover Books on Chemistry) The concepts of equilibrium and entropy thus acquire new significance, and readers discover how thermodynamic parameters may be calculated from spectroscopic data.Įncompassing virtually all of the forms of statistical mechanics customary to undergraduate physical chemistry books, this brief text requires prior acquaintance with only the rudiments of the calculus and a few of the simplest propositions of classical thermodynamics. Starting with an analysis of some very simple microcanonical ensembles, it proceeds to the Boltzmann distribution law and a systematic exploration of the proper formulation, evaluation, and application of partition functions.
This concise, elementary treatment illustrates the ways in which an atomic-molecular perspective yields new insights and powers operative in the realms of macroscopic thermodynamics. This concise, elementary treatment illustrates the ways.) Part Iv Is Also An Addition Which Covers Quantum Systems Such As Ideal Fermi Gas (Free Electrons In Metals), Photon Gas And Ideal Bose Gas (Helium Gas).Elements of Statistical Thermodynamics: Second Edition (Dover Books on Chemistry) In This Part Additions Such As Imperfect Gases, Equilibrium Isotope And Kinetic Isotope Effects And Reactions At The Surfaces Have Been Made, In This Edition. Part Iii Includes Chapters On The Applications Of The Formalism To Real Laboratory Chemical Systems. Part Ii Covers Formalism Of Statistical Mechanism And Its Relation To Thermodynamics As Well As The Statistical Mechanics Of Ensembles, Quantum Statistics And Fluctuations. While The Fundamental Concepts Have Been Developed By First Approach, Concept Of Ensembles Have Been Included To Bring Out The Importance Of This Concept In The Application Of Statistical Thermodynamics To Chemical Systems Where Interparticle Interactions Become Important.Part I Of The Book Deals With The Background Concepts, Fundamentals In Mathematics, Classical Mechanics, Quantum Mechanics And Thermodynamics Which Are Essential For Statistical Mechanics. In This Book Attempt Has Been Made To Take Advantage Of Both Approaches. Some Applications Of Statistical Thermodynamics Have Been Described In Detail With Illustrative Solved Examples.There Are Two Basic Approaches In Statistical Mechanics One Based On The Study Of Independent Particles In An Isolated System And The Other Based On The Concept Of Ensembles. With This, The Theory Has Been Developed In A Simple, Logical And Understandable Way. It Assumes That Readers Have Knowledge Of Basic Thermodynamics And Quantum Mechanics. It Is Intended Primarily For Graduate Students But May Provide Useful Information And Reading To Science And Engineering Students At All Levels. This Is An Introductory Book Which Explains The Foundations Of The Subject And Its Application.
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